April 22, 2004 —
A novel transistor architecture using nanowire memory cells the size of molecules
promises more compact data storage than any existing system.
Researchers at the University of Southern California and the NASA Ames Research
Center have successfully tested a self-assembled molecular memory device they
say has the potential of holding 40 gigabits of data per square centimeter --
a far greater density than any achieved on silicon.
Chongwu Zhou, an assistant professor in the USC Viterbi School department of
electrical engineering, said that because of the self-assembly feature, the ultra
dense memory devices could be less expensive than the silicon flash memories now
widely used in digital cameras, "memory sticks" and other applications.
According to a recent paper in Applied Physics Letters (APL) by Zhou and his
group, the density is achieved by the nanoscale (one millionth of a millimeter)
size of the building blocks used.
In the USC/Ames system is still more compact because each memory cell holds three
bits of data instead of one, by virtue of having eight separate, stable identifiable
electronic states. The system is already quite stable, holding information up
to 600 hours.
"We believe further work can increase the stability still further," said Zhou.
The USC/Ames researchers synthesized nanowires of indium oxide that are 10 nanometers
in diameter and about 2000 nanometers long, by a "laser ablation" process. They
first vaporize a compound containing indium and then in a catalyzed process precipitate
out the indium. The wires form spontaneously as the indium reacts with ambient
oxygen.
The researchers place the nanowires on a thin layer of quartz, and activate them
by submerging them in a solutions of redox materials -- various were tested. All
react with the wires to self-assemble a layer of coating onto the wires creating
transistors. By using different electrical voltages, the resulting transistors
could be stimulated to go into three distinct activated states.
"We repeated tens of cycles for the endurance test for each memory operation
and found that all the levels were distinguishable in the tested cycles," the
authors wrote in their APL paper.
In their paper, the researchers also noted that their cold assembly process "represents
a significant departure from the channel hot electron injection commonly used
for silicon flash memory." Their paper further claims that the USC/Ames process
requires lower power and is inherently less likely to introduce defects that can
cause errors in the device.
Besides Zhou, the team included USC Viterbi School of Engineering graduate students
Chao Li, Bo Lei, Daihua Zhang, Son Han, Tao Tang, Xialei Lu and Zuqin Liu. Team
members from NASA Ames were Wendy Fan, Sylvia Asano, Jie Han and Meyya Meyyappan.
Fan, Asano, and Han's contributions were underwritten by the Eloret Corporation,
a Sunnyvale, Calif. Consulting firm working under contract to NASA.
Besides NASA, the National Science Foundation supported the research.